paper

The nature and evolution of a-C(:H) nanoparticle substructures and speculations on the origin of the 3-4m emission bands

arXiv:2509.13119 · doi:10.1051/0004-6361/202556756

Abstract

The nature and evolution of hydrocarbonaceous grains within interstellar and circumstellar media is still far from resolved, perhaps owing to the rather complex nature of their seemingly simple binary atomic compositions. This work explores the fine details of amorphous hydrocarbon nanoparticle, a-C(:H), composition and the evolution of the inherent sub-structures under extreme conditions, focusing on the characteristic CH bands in the 3-4 micron wavelength region. Particular attention is paid to the role of dehydrogenation and its effects on the sp^3 and sp^2 hybridisations, leading to an extensive conjugated domain functionalisation of the contiguous structural network within a-C(:H) nanoparticles. Qualitatively this approach is able to explain the origin and evolution, including the appearance and disappearance, of emission bands observed in the 3-4 micron wavelength regime without a significant aromatic moiety content within the structures. A diatomic a-C(:H) phase is likely at the heart of the observed dust evolution in the interstellar medium, and circumstellar and photodissociation regions, as observed at short wavelengths. It appears that we have some way to go in fully understanding these complex materials. Much laboratory work will be required in order to elucidate their chemical and structural evolution at nanoparticle sizes under extreme conditions.

9 pages, 2 tables and 5 figures. Accepted for publication in A&A 14 September 2025

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