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Recent Advances in Unconventional Ferroelectrics and Multiferroics

arXiv:2509.00384 · doi:10.1002/adma.202507070

Abstract

Emerging ferroic materials may pave a new way to next-generation nanoelectronic and spintronic devices due to their interesting physical properties. Here, we systematically review unconventional ferroelectric systems, from Hf-based and elementary ferroelectrics to stacking ferroelectricity, polar metallicity, fractional quantum ferroelectricity, wurtzite-type ferroelectricity, and freestanding membranes ferroelectricity. Moreover, multiferroic materials are reviewed, particularly the interplay between novel magnetic states and ferroelectricity, as well as ferrovalley-ferroelectric coupling. Finally, we conclude by discussing current challenges and future opportunities in this field.

62 pages, 13 figures

Recent Advances in Unconventional Ferroelectrics and Multiferroics · wovepaper