Superconducting gap in covalent bismuth dihydride BiH${}_2$ under extreme conditions

Abstract

Hydride superconductors at megabar pressures provide a promising platform for exploring room-temperature superconductivity. However, their superconducting gaps remain largely inaccessible to conventional spectroscopic due to diamond anvil cell constraints and minute sample dimensions. Here we develop a pulsed current method and apply it to covalent BiH${}_2$ synthesized at 157--176 GPa. BiH${}_2$ exhibits superconductivity at 58--70 K and upper critical fields of 11--17 T, substantially lower than those of many clathrate superhydrides, corresponding to a relatively long coherence length and an experimentally accessible critical current density. Short rectangular pulses minimize sustained Joule heating and enable currents up to 160 mA, allowing $J_c(T)$ to be measured in the low-temperature regime down to 2 K at 176 GPa. The normalized critical-current response remains reproducible between two measurement runs and is better described by a two-scale $s$-wave model than by single-gap $s$- or $d$-wave models, yielding effective energy scales of approximately 6.9 and 1.5 meV. Fully anisotropic Migdal--Eliashberg calculations yield a single highly anisotropic gap, suggesting that the two-gap behavior observed experimentally originates from gap anisotropy rather than two independent gaps. These results establish pulsed critical-current measurements as a practical gap-sensitive transport probe under extreme pressure and, with further increases in peak-current capability, provide a route toward investigating room-temperature hydrides such as La--Sc--H.

12 pages, 5 figures