High pressure structural and lattice dynamics study of α-In${}_2$Se${}_3$

Abstract

Layered $\alpha$-In${}_2$Se${}_3$has been studied using a concomitant in-situ synchrotron angle dispersive powder x-ray diffraction and Raman spectroscopy study in a diamond anvil cell up to 60+ GPa, at room temperature. Helium, that remains fairly hydrostatic up to the highest pressure in this study, was used as the pressure-transmitting medium. The results from both experimental methods reveal a pressure-induced structural phase transition from $\alpha$-In${}_2$Se${}_3$ to a monoclinic $\beta$'-In2Se3 structure at $\approx$1 GPa, in agreement with previous studies. Based on our detailed measurements using both experimental techniques and F-f formalism, the $\beta$'-In${}_2$Se${}_3$ structure remains stable up to 45 GPa, without a clear indication of a phase transition towards the previously reported $\beta$-In2Se3 phase. Above this pressure, In${}_2$Se${}_3$ adopts a disordered solid-solution-like orthorhombic structure, phase IV. The results are discussed in comparison with the relevant previous studies of $\alpha$-In${}_2$Se${}_3$ under pressure.

16 Pages, 6 figures