Observation of quantum oscillations, linear magnetoresistance, and crystalline electric field effect in quasi-two-dimensional PrAgBi${}_2$

Abstract

We report the magnetic and magnetotransport properties with electronic band structure calculation of the Bi square net system PrAgBi${}_2$. The magnetization and heat capacity data confirm the presence of a crystalline electric field (CEF) effect in PrAgBi${}_2$. Analysis of the CEF effect using a multilevel energy scheme reveals that the ground state of PrAgBi${}_2$ consists of five singlets and two doublets. The de Haas-van Alphen (dHvA) quantum oscillations data show a single frequency with a very small cyclotron effective mass of approximately 0.11 $m_e$. A nontrivial Berry phase is also observed from the quantum oscillations data. The magnetotransport data shows linear and unsaturated magnetoresistance, reaching up to 1060\% at 2 K and 9 T. Notably, there is a crossover from a weak-field quadratic dependence to a high-field linear dependence in the field-dependent magnetoresistance data. The crossover critical field $B^{\ast }$ follows the quadratic temperature dependence, indicating the existence of Dirac fermions. The band structure calculation shows several Dirac-like linear band dispersions near the Fermi level and a Dirac point close to the Fermi level, located at the Brillouin zone boundary. \textit{Ab inito} calculations allowed us to ascribe the observed dHvA oscillation frequency to a particular feature of the Fermi surface. Our study suggests layered PrAgBi${}_2$ is a plausible candidate for hosting the CEF effect and Dirac fermion in the Bi square net.

12 pages, 6 figures

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