Terahertz control of surface topology probed with subatomic resolution

Abstract

Light-induced phase transitions offer a method to dynamically modulate topological states in bulk complex materials. Yet, next-generation devices demand nanoscale architectures with contact resistances near the quantum limit and precise control over local electronic properties. The layered material WTe${}_2$ has gained attention as a likely Weyl semimetal, with topologically protected linear electronic band crossings hosting massless chiral fermions. Here, we demonstrate a topological phase transition facilitated by light-induced shear motion of a single atomic layer at the surface of bulk WTe${}_2$, thereby opening the door to nanoscale device concepts. Ultrafast terahertz fields enhanced at the apex of an atomically sharp tip resonantly couple to the key interlayer shear mode of WTe${}_2$ via a ferroelectric dipole at the interface, inducing a structural phase transition at the surface to a metastable state. Subatomically resolved differential imaging, combined with hybrid-level density functional theory, reveals a shift of 7 $\pm$ 3 picometres in the top atomic plane. Tunnelling spectroscopy links electronic changes across the phase transition with the electron and hole pockets in the band structure, suggesting a reversible, light-induced annihilation of the topologically-protected Fermi arc surface states in the top atomic layer.

References in corpus (13)

• Nonthermal pathways to ultrafast control in quantum materials
• Light-induced emergent phenomena in 2D materials and topological materials
• Berry curvature memory through electrically driven stacking transitions
• Topology and geometry under the nonlinear electromagnetic spotlight
• Experimental observation of anisotropic Adler-Bell-Jackiw anomaly in type-II Weyl semimetal WTe${}_{1.98}$ crystals at the quasi-classical regime
• Mode-resolved reciprocal space mapping of electron-phonon interaction in the Weyl semimetal candidate Td-WTe${}_2$
• Atomic-Scale Terahertz Near Fields for Ultrafast Tunnelling Spectroscopy
• Surface Fermi arc connectivity in the type-II Weyl semimetal candidate WTe${}_2$
• Electronic properties of type-II Weyl semimetal WTe${}_2$. A review perspective
• Manipulating Weyl quasiparticles by orbital-selective photoexcitation in WTe2
• T${}_d$ to 1T${}^{\prime }$ structural phase transition in WTe${}_2$ Weyl semimetal
• Two phase transitions driven by surface electron-doping in WTe${}_2$
• Traversing double-well potential energy surfaces: photoinduced concurrent intralayer and interlayer structural transitions in XTe2 (X=Mo, W)

Cited by in corpus (1)

• Influence of atomic-scale defects on coherent phonon excitations by THz near fields in an STM