Single parameter aging and density scaling

Abstract

In a recent paper, Di Lisio et al. [J. Chem. Phys. 159 064505 (2023)] analyzed a series of temperature down-jumps using the single-parameter aging (SPA) ansatz combined with a specific assumption about density scaling in the out-of-equilibrium system and did not find a good prediction for the largest down-jumps. In this paper we show that SPA in its original form does work for all their data including large jumps of ΔT > 20 K. Furthermore, we discuss different approaches to the extension of the density scaling concept to out-of-equilibrium systems.