Evidence of surface $p$-wave superconductivity and higher-order topology in MoTe${}_2$

Abstract

Exploration of nontrivial superconductivity and electronic band topology is at the core of condensed matter physics and applications to quantum information. The transition-metal dichalcogenide (TMDC) MoTe${}_2$ has been proposed as an ideal candidate to explore the interplay between topology and superconductivity, but their studies remain limited regarding the required high-pressure environments. Here, we observe proximity-induced surface $p$-wave superconductivity, and investigate the higher-order topological nature of MoTe${}_2$ in its 1T${}^{\prime }$ phase, which emerges from the T${}_d$ phase through a high-pressure-induced topological phase transition. Using surface-sensitive soft-point-contact Andreev reflection spectroscopy, we confirm the emergence of surface $s+p$-wave superconductivity via the BTK model as well as a zero-bias conductance peak. Such surface $p$-wave superconductivity emerges via the proximity effect between an $s$-wave superconducting band and a second-order topological band, which is protected by the time-reversal and inversion symmetries. The temperature dependence of the surface $p$-wave superconducting gap shows a correlation with that of the bulk $s$-wave gap, as well as its suppression by an external magnetic field or a reduction in pressure, implying its proximity-induced origin. Moreover, we suggest that the topological hinge states, derived from second-order topological bands, evolve into zero-energy Majorana corner states in this proximity-effect-induced third-order topological superconducting phase. These results demonstrate the potential realization of topological superconductivity in MoTe${}_2$, thus opening a pathway for studying various topological natures of TMDC materials.