The Composition and Chemistry of Titan's Atmosphere
arXiv:2402.17116 · doi:10.1021/acsearthspacechem.2c00041
Abstract
In this article I summarize the current state of knowledge about the composition of Titan's atmosphere, and our current understanding of the suggested chemistry that leads to that observed composition. I begin with our present knowledge of the atmospheric composition, garnered from a variety of measurements including Cassini-Huygens, the Atacama Large Millimeter/submillimeter Array (ALMA), and other ground and space-based telescopes. This review focuses on the typical vertical profiles of gases at low latitudes, rather than global and temporal variations. The main body of the paper presents a chemical description of how complex molecules are believed to arise from simpler species, considering all known 'stable' molecules - those that have been uniquely identified in the neutral atmosphere. The last section of the paper is devoted to the gaps in our present knowledge of Titan's chemical composition and how further work may fill those gaps.
177 pages, 45 figures
References in corpus (36)
- The 2014 KIDA network for interstellar chemistry
- Pure hydrocarbon cycles in TMC-1: Discovery of ethynyl cyclopropenylidene, cyclopentadiene and indene
- Discovery of benzyne, o-C6H4, in TMC-1 with the QUIJOTE line survey
- GCM simulations of Titan's middle and lower atmosphere and comparison to observations
- Confirming interstellar C using the Hubble Space Telescope
- Phosphine as a Biosignature Gas in Exoplanet Atmospheres
- Early Science from GOTHAM: Project Overview, Methods, and the Detection of Interstellar Propargyl Cyanide (HCCCHCN) in TMC-1
- Characterizing Exoplanet Habitability
- Origin of Earth's water: sources and constraints
- Ethyl cyanide on Titan: Spectroscopic detection and mapping using ALMA
- Infrared Spectra and Optical Constants of Astronomical Ices: II. Ethane and Ethylene
- A new astrobiological model of the atmosphere of Titan
- Aromatics and Cyclic Molecules in Molecular Clouds: A New Dimension of Interstellar Organic Chemistry
- ALMA measurements of the HNC and HCN distributions in Titan's atmosphere
- Titan's Prolific Propane: The Cassini CIRS Perspective
- Detection of Cyclopropenylidene on Titan with ALMA
- Laboratory Investigations of Titan Haze Formation: In Situ Measurement of Gas and Particle Composition
- A study of C4H3N isomers in TMC-1: line by line detection of HCCCH2CN
- Upper limits for undetected trace species in the stratosphere of Titan
- Seasonal changes in the middle atmosphere of Titan from Cassini/CIRS observations: temperature and trace species abundance profiles from 2004 to 2017
- Detection of Propadiene on Titan
- Surface Energy of the Titan Aerosol Analog "Tholin"
- A Consistent Reduced Network for HCN Chemistry in Early Earth and Titan Atmospheres: Quantum Calculations of Reaction Rate Coefficients
- Detection of CHCN in Titan's Atmosphere
- HCN production in Titan's Atmosphere: Coupling quantum chemistry and disequilibrium atmospheric modeling
- Coexistence of CH4, CO2 and H2O in exoplanet atmospheres
- Mapping Vinyl Cyanide and Other Nitriles in Titan's Atmosphere Using ALMA
- Nitrogen-containing Anions and Tholin Growth in Titan's Ionosphere: Implications for Cassini CAPS-ELS Observations
- Detection of Dynamical Instability in Titan's Thermospheric Jet
- Upper limits for PH3 and H2S in Titan's Atmosphere from Cassini CIRS
- Positive Ion Chemistry in an N-CH Plasma Discharge: Key Precursors to the Growth of Titan Tholins
- Ethane in Titan's Stratosphere from Cassini CIRS Far- and Mid-Infrared Spectra
- Experimental Characterization of the Pyridine:Acetylene Co-crystal and Implications for Titan's Surface
- Variability in Titan's Mesospheric HCN and Temperature Structure as Observed by ALMA
- Re-Analysis of the Cassini RPWS/LP Data in Titan's Ionosphere: 1. Detection of Several Electron Populations
- Spitzer IRS Observations of Titan as a Precursor to JWST MIRI Observations
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