On Supercapacitors Time-Domain Spectroscopy. C/R Characteristic Slope

Abstract

A novel time-domain technique for supercapacitor characterization is developed, modeled numerically, and experimentally tested on a number of commercial supercapacitors. The method involves momentarily shorting a supercapacitor for a brief duration, denoted as $\tau$, and measuring first $\int Idt$ and second $\int I^{2}dt$ moments of current along with the potential before and after shorting. The effective $C(\tau )$ and $R(\tau )$ are then obtained from charge preservation and energy dissipation invariants. A linear behavior in $[R(\tau ),C(\tau )]$ parametric plot is observed by several orders of $\tau$. This gives a $C/R$ characteristic slope: how much $\Delta C$ we can ``gain'' if we are ready to ``lose'' $\Delta R$ in internal resistance. The $C/R$ characteristic slope characterizes possible energy and power properties of the device in terms of materials and technology used, this is a measure of supercapacitor perfection. The technique has been proven with experimental measurements and then validated through computer modeling, analytic analysis, and impedance spectroscopy on a number of circuit types: transmission line, binary tree, etc., a new n-tree element (nTE) is introduced. The approach offers an alternative to low-frequency impedance spectroscopy and methods outlined in the IEC 62391 standard. It provides valuable insights into the performance and characteristics of supercapacitors.

The technique from arXiv:1908.02559 was extended to obtain R(τ). A generalization from [Re Z(ω),Im Z(ω)] to [R(τ),C(τ)] is the main concept of Time Domain Spectroscopy