Amine-Modified ZIF-8 for Enhanced CO${}_2$ Capture: Synthesis, Characterization and Performance Evaluation

Abstract

The urgent need for sustainable and innovative approaches to mitigate the increasing levels of atmospheric CO${}_2$ necessitates the development of efficient methods for its removal. In this study, we focus on the synthesis and functionalization of metal-organic framework (MOF) ZIF-8 at room temperature to enhance its capacity for CO${}_2$ capture. Specifically, we investigated the impact of four amino-compounds, namely tetraethylenepentamine (TEPA), hexadecylamine (HDA), ethanolamine (ELA), and cyclopropylamine (CPA), on the chemical structure, size, surface area and porosity and CO${}_2$ capturing of ZIF-8 powder. By varying concentrations of the amino-compounds, we examined their influence on the ZIF-8 properties. These results highlight the potential of simple synthesis and functionalization techniques for MOFs in enhancing their CO${}_2$ capture capabilities. The findings from this study offer new opportunities for the development of strategies to mitigate CO${}_2$ emissions using MOFs.