Electronic matrix elements for parity doubling in YbOH molecule

Abstract

YbOH molecule is one of the most sensitive systems for the electron electric dipole moment ($e$EDM) searches. The $e$EDM-induced energy shift is proportional to polarization ($P$) of the molecule. In Ref. [A. Petrov and A. Zakharova, Phys. Rev. A 105, L050801 (2022)] was shown that the value of l-doubling and spin-rotation splitting directly influences the maximum value of $P$. Recently in Ref. [Jadbabaie, Y. Takahashi, N. H. Pilgram, C. J. Conn, Y. Zeng, C. Zhang, and N. R. Hutzler, New Journal of Physics 25, 073014 (2023)] the corresponding energy levels was determined experimentally. We introduced electronic matrix elements in Hund's case $c$ coupling scheme to reproduce experimental energy levels and calculated $P$ as function of external electric field.

References in corpus (23)

• A new bound on the electron's electric dipole moment
• Precision Measurement of Time-Reversal Symmetry Violation with Laser-Cooled Polyatomic Molecules
• Searching for New Physics beyond the Standard Model in Electric Dipole Moment
• Laser-Cooled Polyatomic Molecules for Improved Electron Electric Dipole Moment Searches
• CKM benchmarks for electron EDM experiments
• Polyatomic candidates for cooling of molecules with lasers from simple theoretical concepts
• Large long-distance contributions to the electric dipole moments of charged leptons in the standard model
• Laser-coolable polyatomic molecules with heavy nuclei
• Quark level and hadronic contributions to the electric dipole moment of charged leptons in the standard model
• Enhancement factor for the electric dipole moment of the electron in the BaOH and YbOH molecules
• Quantum Control of Trapped Polyatomic Molecules for eEDM Searches
• Ab initio study of parity and time-reversal violation in laser-coolable triatomic molecules
• Theoretical study of ${}^{173}$YbOH to search for the nuclear magnetic quadrupole moment
• Enhanced sensitivity of the electron electric dipole moment from YbOH: The role of theory
• The pure rotational spectrum of YbOH
• Hyperfine and Zeeman interactions of the $a(1){[}^3{\Sigma }_1^{+}]$ state of PbO
• Fine and hyperfine interactions in ${}^{171}$YbOH and ${}^{173}$YbOH
• Sensitivity of the YbOH molecule to $\mathcal{P}$,$\mathcal{T}$-odd effects in the external electric field
• Characterizing the Fundamental Bending Vibration of a Linear Polyatomic Molecule for Symmetry Violation Searches
• Electronic structure of ytterbium monohydroxide molecule to search for axionlike particles
• Rovibrational structure of the Ytterbium monohydroxide molecule and the $\mathcal{P}$,$\mathcal{T}$-violation searches
• $\mathcal{P}$,$\mathcal{T}$-odd energy shifts of the ${}^{173}$YbOH
• Impact of the ligand deformation on the $\mathcal{P}$,$\mathcal{T}$-violation effects in the YbOH molecule