Suppression of stacking order with doping in 1T-TaS${}_{2-x}$Se${}_x$

Abstract

In 1T-TaS${}_{2-x}$Se${}_x$, the charge density wave (CDW) state features a star of David lattice that expands across layers as the system becomes commensurate on cooling. The layers can also order along the c-axis and different stacking orders have been proposed. Using neutron scattering on powder samples, we compared the stacking order previously observed in 1T-TaS${}_2$ as the system is doped with Se. While at low temperature, a 13c layer sequence stacking was observed in TaS${}_2$, this type of ordering was not evident with doping. Doping with Se results in a nearly commensurate state with the Mott state suppressed which may be linked to the absence of the layer stacking.

5 pages, 3 figures