Magnetic Optical Rotation from Real-Time Simulations in Finite Magnetic Fields

Abstract

We present a numerical approach to magnetic optical rotation based on real-time time-dependent electronic-structure theory. Not relying on perturbation expansions in the magnetic-field strength, the formulation allows us to test the range of validity of the linear relation between the rotation angle per unit path length and the magnetic-field strength that was established empirically by Verdet 160 years ago. Results obtained from time-dependent coupled-cluster and time-dependent current density-functional theory are presented for the closed-shell molecules H2, HF, and CO in magnetic fields up to 55 kT at standard temperature and pressure conditions. We find that Verdet's linearity remains valid up to roughly 10-20 kT, above which significant deviations from linearity are observed. Among the three current density-functional approximations tested in this work, the current-dependent Tao-Perdew-Staroverov-Scuseria hybrid functional performs the best in comparison with time-dependent coupled-cluster singles and doubles results for the magnetic optical rotation.

References in corpus (4)

• Numerical stability of time-dependent coupled-cluster methods for many-electron dynamics in intense laser pulses
• A DZ white dwarf with a 30 MG magnetic field
• Linear and nonlinear optical properties from TDOMP2 theory
• Adiabatic extraction of nonlinear optical properties from real-time time-dependent electronic-structure theory

Cited by in corpus (1)

• Equation-of-motion coupled-cluster variants in combination with perturbative triples corrections in strong magnetic fields