Autoionization of high-$\ell$ core-excited Rydberg states of alkaline-earth-metal atoms

Abstract

The autoionization of core-excited Rydberg states is theoretically studied for a broad range of principal and angular-momentum quantum numbers $n$ and $\ell$ in alkaline-earth-metal atoms. We combined two theoretical methods to calculate accurate autoionization rates for $n=10-65$ and $\ell =0-45$ over the 100 orders of magnitude that they span. The strong interaction between the two valence electrons for low $\ell$ states is treated from first principles with configuration interaction with exterior complex scaling, while at large $\ell$ the weak correlation is described by a perturbative approach and arbitrary-precision floating-point arithmetics. The results, which we benchmark against available experimental data, provide autoionization rates for the $N{p}_{1/2,3/2}$ and, when applicable, $(N-1)d_{3/2,5/2}$ ion-core states of Mg, Ca and Sr ($N=3-5$). Using the extensive set of calculated data, we analyze the dependence of the rates on $\ell$ and identify five general laws of the autoionization of high-$\ell$ states. An empirical formula describing the scaling of the rates with $\ell$ is suggested.

16 pages, 11 figures

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