Unexpected Gaussian line shapes reveal electron-adsorbate interaction as dominant broadening mechanism in quantum corrals

Abstract

Understanding the factors influencing the lifetime of electronic states in artificial quantum structures is of great significance for advancing quantum technologies. This study focuses on CO-based quantum corrals on Cu(111). Tunneling spectroscopy measurements reveal a strong correlation between the size of the quantum corral and spectral width, characterized by a predominant Gaussian line shape. We attribute this dominant Gaussian-shaped lifetime broadening to the interaction of surface state electrons with the corral boundary. To further investigate this phenomenon, we constructed corrals of varying wall densities. Our findings indicate that elastic processes, such as tunneling, are more sensitive to wall density than coupling to the bulk.

Major revision of the discussion and inclusion of new data for corrals with different wall densities. Major expansion of the supplemental material. The results for the line shape analysis (line scans) stayed the same