The magnesium paradigm in IRC+10216: Discovery of MgC${}_4$H${}^{+}$, MgC${}_3$N${}^{+}$, MgC${}_6$H${}^{+}$, and MgC${}_5$N${}^{+}$

Abstract

We found four series of harmonically related lines in IRC\,+10216 with the Yebes\,40m and IRAM\,30m telescopes. The first series corresponds to a molecule with a rotational constant, $B$, of 1448.5994$\pm$0.0013 MHz and a distortion constant, $D$, of 63.45$\pm$1.15 Hz and covers upper quantum numbers from $J_u$=11 up to 33 (B1449). The second series is fitted with $B$=1446.9380$\pm$0.0098 MHz and $D$=91$\pm$23 Hz and covers upper quantum numbers from $J_u$=11 up to 17 (B1447). The third series is fitted with $B$=598.7495$\pm$0.0011 MHz and D=6.13$\pm$0.43 Hz and covers quantum numbers from $J_u$=26 up to 41 (B599). Finally, the frequencies of the last series of lines can be reproduced with $B$=594.3176$\pm$0.0026 MHz and $D$=4.92$\pm$1.16 Hz (B594). The large values of $D$ point toward four metal-bearing carriers. After exploring all plausible candidates containing Na, Al, Mg, and other metals, our ab initio calculations indicate that the cations MgC${}_4$H${}^{+}$, MgC${}_3$N${}^{+}$, MgC${}_6$H${}^{+}$, and MgC${}_5$N${}^{+}$ must be the carriers of B1449, B1447, B599, and B594, respectively. These cations could be formed by the radiative association of Mg${}^{+}$ with C${}_4$H, C${}_3$N, C${}_6$H, and C${}_5$N, respectively. We calculated the radiative association rate coefficient of Mg${}^{+}$ with C${}_4$H, C${}_3$N, C${}_6$H, and C${}_5$N and incorporated them in our chemical model. The results confirm that the Mg-bearing cations can be formed through these radiative association reactions in the outer layers of IRC\,+10216. This is the first time that cationic metal-bearing species have been found in space. These results provide a new paradigm on the reactivity of ionized metals with abundant radicals and open the door for further characterization of similar species in metal-rich astrophysical environments.