Evolution of complex magnetic phases and metal-insulator transition through Nb substitution in La${}_{0.5}$Sr${}_{0.5}$Co${}_{1-x}$Nb${}_x$O${}_3$

Abstract

We report the evolution of structural, magnetic, transport, and electronic properties of bulk polycrystalline La${}_{0.5}$Sr${}_{0.5}$Co${}_{1-x}$Nb${}_x$O${}_3$ ($x=$ 0.025--0.25) samples. The Rietveld refinement of the x-ray diffraction patterns with R$\bar{3}$c space group reveals that the lattice parameters and rhombohedral distortion monotonously increase with the Nb${}^{5+}$(4$d^0$) substitution ($x$). The magnetic susceptibility exhibits a decrease in the magnetic ordering temperature and net magnetization with $x$, which manifests that the Nb substitution dilutes the ferromagnetic (FM) double exchange interaction and enhances the antiferromagnetic (AFM) super-exchange interaction. Interestingly, for the $x>$ 0.1 samples the FM order is completely suppressed and the emergence of a glassy state is clearly evident. Moreover, the decrease in the coercivity (H${}_{\mathrm{C}}$) and remanence (M${}_{\mathrm{r}}$) with $x$ in the magnetic isotherms measured at 5~K further confirms the dominance of AFM interactions and reduction of FM volume fraction for the $x>$ 0.1 samples. More interestingly, we observe resistivity minima for the $x=$ 0.025 and 0.05 samples, which are analyzed using the quantum corrections in the conductivity, and found that the weak localization effect dominates over the renormalized electron-electron interactions in the 3D limit. Further, a semiconducting resistivity behavior is obtained for $x>$ 0.05, which follows the Arrhenius law at high temperatures ($\sim$160--320~K), and the 3D-variable range hopping prevails in the low-temperature region ($<$160~K). The core-level photoemission spectra confirm the valence state of constituent elements and the absence of Co${}^{2+}$ is discernible.

arXiv commentsubmitted

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