Length-independent quantum transport through topological band states of graphene nanoribbons

Abstract

Atomically precise graphene nanoribbons (GNRs) have emerged as promising candidates for nanoelectronic applications due to their widely tunable energy band gaps resulting from lateral quantum confinement and edge effects. Here we report on the electronic transport characterization of an edge-modified GNR suspended between the tip of a scanning tunneling microscope (STM) and a Au(111) substrate. Differential conductance measurements on this metal-GNR-metal junction reveal loss-less transport properties (inverse decay length $\beta <0.001/\stackrel{\circ }{\mathrm{A}}$) with high conductance ($\sim 0.1$ G${}_0$) at low voltages (50 meV) over long distances ($z>10$ nm). The transport behavior is sensitive to the coupling between ribbon and electrodes, an effect that is rationalized using tight-binding and density functional theory simulations. From extensive modelling we infer that the length-independent transport is a manifestation of band transport through topological valence states, which originate from the zigzag segments on the GNR edges.

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