Phonon softening and slowing down of charge-density-wave fluctuations in BaNi${}_2$As${}_2$

Abstract

BaNi${}_2$As${}_2$ is a nonmagnetic analogue of the iron pnictide superconductors, and in its tetragonal state exhibits an incommensurate charge-density-wave (IC-CDW) and a sizable elastoresistance. In this work, phonons in BaNi${}_2$As${}_2$ associated with the IC-CDW and uniform in-plane lattice distortions are investigated using high-resolution inelastic X-ray scattering. The in-plane transverse acoustic phonons reveal no softening at temperatures where the elastoresistance increases strongly, indicating the latter to be electronically driven. Systematic phonon measurements reveal the IC-CDW occurs in two stages upon cooling: underdamped phonons first soften to zero energy well above the IC-CDW ordering temperature, then the resulting quasielastic IC-CDW fluctuations gradually slow down and coalesce into the static IC-CDW order. A possible origin for our observations is the IC-CDW in tetragonal BaNi${}_2$As${}_2$ being uniaxial, which provides an additional Ising degree of freedom favorable for disordered IC-CDW modulations, and accounts for the elastoresistance through a weak coupling to the lattice.

Supplemental Materials available upon request