Perturbative Steady States of Completely Positive Quantum Master Equations

Abstract

The Lindblad form guarantees complete positivity of a Markovian quantum master equation (QME). However, its microscopic derivation for a quantum system weakly interacting with a thermal bath requires several approximations, which may result in inaccuracies in the QME. Recently, various Lindbladian QMEs were derived without resorting to the secular approximation from the Redfield equation which does not guarantee the complete positivity. Here we explicitly calculate, in a perturbative manner, the equilibrium steady states of these Lindbladian QMEs. We compare the results with the steady state of the Redfield equation obtained from an analytic continuation method, which coincides with the so-called mean force Gibbs (MFG) state. The MFG state is obtained by integrating out the bath degrees of freedom for the Gibbs state of the total Hamiltonian. We explicitly show that the steady states of the Lindbladian QMEs are different from the MFG state. Our results indicate that manipulations of the Redfield equation needed to enforce complete positivity of a QME drives its steady state away from the MFG state. We also find that, in the high-temperature regime, both the steady states of the Lindbladian QMEs and MFG state reduce to the same Gibbs state of a system Hamiltonian under certain conditions.

14 pages, 3 figures, 1 table

References in corpus (13)

• Many body localization and thermalization in quantum statistical mechanics
• Open quantum system dynamics and the mean force Gibbs state
• Unified Gorini-Kossakowski-Lindblad-Sudarshan quantum master equation beyond the secular approximation
• The equilibrium states of open quantum systems in the strong coupling regime
• Fundamental limitations in Lindblad descriptions of systems weakly coupled to baths
• Generalized Gibbs state with modified Redfield solution: Exact agreement up to second order
• Weak and ultrastrong coupling limits of the quantum mean force Gibbs state
• A thermodynamically consistent Markovian master equation beyond the secular approximation
• The Accuracy of Perturbative Master Equations
• Dynamics of the Density Matrix in Contact with a Thermal Bath and the Quantum Master Equation
• Lindbladian approximation beyond ultra-weak coupling
• Canonically consistent quantum master equation
• Finite coupling effects in double quantum dots near equilibrium

Cited by in corpus (8)

• Full counting statistics and coherences: fluctuation symmetry in heat transport with the Unified quantum master equation
• A time-dependent regularization of the Redfield equation
• Effective-Hamiltonian theory: An approximation to the equilibrium state of open quantum systems
• Invalidation of the Bloch-Redfield Equation in Sub-Ohmic Regime via a Practical Time-Convolutionless Fourth-Order Master Equation
• Structure of the Hamiltonian of mean force
• The hidden negative differential thermal conductance
• Gate-Based Initialization and Fidelity in Correlated Open Quantum Systems
• Structure of Quantum Mean Force Gibbs States for Coupled Harmonic Systems