Study of excited electronic states of the ${}^{39}$KCs molecule correlated with the K($4^2$S)+Cs($5^2$D) asymptote: experiment and theory

Abstract

Using the polarisation labelling spectroscopy, we performed the detailed analysis of the level structure of excited electronic states of the ${}^{39}$KCs molecule in the excitation energy interval between 17500~cm${}^{-1}$ and 18600~cm${}^{-1}$ above the $v=0$ level of the $X^1{\Sigma }^{+}$ ground state. We prove that the observed states are strongly coupled by spin-orbit interaction above 18200~cm${}^{-1}$, as manifested by numerous perturbations in the recorded spectra. The spectra are interpreted with the guidance of accurate electronic structure calculations on KCs, including potential energy curves, transition electric dipole moments, and representation of the spin-orbit interaction with a quasi-diabatic effective Hamiltonian approach. The agreement between theory and experiment is found remarkable, clearly discriminating among the available theoretical data. This study confirms the accuracy of the polarisation labelling spectroscopy to analyse highly-excited electronic molecular states which present a dense level structure.

26 pages, 10 figures, laser spectroscopy, KCs molecules electronic states, potential energy curves, ab initio calculations

References in corpus (4)

• Modeling the adiabatic creation of ultracold, polar ${}^{23}\mathrm{N}{\mathrm{a}}^{40}\mathrm{K}$ molecules
• Observation of interspecies Feshbach resonances in an ultracold ${}^{39}$K-${}^{133}$Cs mixture and refinement of interaction potentials
• Feshbach resonances, molecular bound states and prospects of ultracold molecule formation in mixtures of ultracold K and Cs
• Dynamic dipole polarizabilities of heteronuclear alkali dimers: optical response, trapping and control of ultracold molecules