Complex analysis of divergent perturbation theory at finite temperature
arXiv:2203.02377 · doi:10.1063/5.0091442
Abstract
We investigate the convergence properties of finite-temperature perturbation theory by considering the mathematical structure of thermodynamic potentials using complex analysis. We discover that zeros of the partition function lead to poles in the internal energy and logarithmic singularities in the Helmholtz free energy which create divergent expansions in the canonical ensemble. Analysing these zeros reveals that the radius of convergence increases for higher temperatures. In contrast, when the reference state is degenerate, these poles in the internal energy create a zero radius of convergence in the zero-temperature limit. Finally, by showing that the poles in the internal energy reduce to exceptional points in the zero-temperature limit, we unify the two main mathematical representations of quantum phase transitions.
8 pages, 5 figures
References in corpus (9)
- The physics of exceptional points
- Observation of Lee-Yang zeros
- Coulomb analogy for nonhermitian degeneracies near quantum phase transitions
- Perturbation Theory in the Complex Plane: Exceptional Points and Where to Find Them
- Finite-temperature second-order many-body perturbation theory revisited
- Finite-Temperature Many-Body Perturbation Theory in the Canonical Ensemble
- Lee-Yang theory of criticality in interacting quantum many-body systems
- Hartree-Fock Critical Nuclear Charge in Two-Electron Atoms
- Finite-temperature many-body perturbation theory for electrons: Algebraic recursive definitions, second-quantized derivation, linked-diagram theorem, general-order algorithms, grand canonical and canonical ensembles