Thixotropic spectra and Ashby-style charts for thixotropy

Abstract

There is no universal model for thixotropy, and comparing thixotropic effects between different fluids is a subtle yet challenging problem. We introduce a generalized (model-insensitive) framework for comparing thixotropic properties based on thixotropic spectra. A superposition of exponential stress modes distributed over thixotropic timescales is used to quantify buildup and breakdown times and mode strengths in response to step-change input. This mathematical framework is tested with several experimental step-shear rate data on colloidal suspensions. Low-dimensional metrics based on moments of the distribution reveal characteristic average thixotropic properties which are visualized on Ashby-style diagrams. This method outlines a framework for describing thixotropy across a diverse range of microstructures, supporting scientific studies as well as material selection for engineering design applications.

arXiv comment27 pages, 7 figures, Supplementary Information included in ancillary files as SI.pdf

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Cited by in corpus (2)

• New insights on carbon black suspension rheology -- anisotropic thixotropy and anti-thixotropy
• The Mnemosyne Number and the Rheology of Remembrance