Fluctuating temperature outside superstatistics: thermodynamics of small systems

Abstract

The existence of fluctuations of temperature has been a somewhat controversial topic in thermodynamics but nowadays it is recognized that they must be taken into account in small, finite systems. Although for nonequilibrium steady states superstatistics is becoming the \textit{de facto} framework for expressing such temperature fluctuations, some recent results put into question the idea of temperature as a phase space observable. In this work we present and explore the statistics that describes a part of an isolated system, small enough to have well-defined uncertainties in energy and temperature, but lacking a superstatistical description. These results motivate the use of the so-called fundamental temperature as an observable and may be relevant for the statistical description of small systems in physical chemistry.

References in corpus (2)

• Temperature fluctuations in canonical systems: Insights from molecular dynamics simulations
• Thermodynamic fluctuation relation for temperature and energy

Cited by in corpus (5)

• Superstatistics as the thermodynamic limit of driven classical systems
• Fundamental temperature exclusively determines the validity of superstatistics
• Temperature fluctuations in finite systems: Application to the one-dimensional Ising chain
• Kappa distributions in the framework of superstatistics
• A classification of nonequilibrium steady states based on temperature correlations