Oxygen Vacancies in Niobium Pentoxide as a Source of Two-Level System Losses in Superconducting Niobium

Abstract

We identify a major source of quantum decoherence in three-dimensional superconducting radio-frequency (SRF) resonators and two-dimensional transmon qubits composed of oxidized niobium: oxygen vacancies in the niobium pentoxide which drive two-level system (TLS) losses. By probing the effect of sequential \textit{in situ} vacuum baking treatments on the RF performance of bulk Nb SRF resonators and on the oxide structure of a representative Nb sample using time-of-flight secondary ion mass spectrometry (ToF-SIMS), we find a non-monotonic evolution of cavity quality factor $Q_0$ which correlates with the interplay of Nb\textsubscript{2}O\textsubscript{5} vacancy generation and oxide thickness reduction. We localize this effect to the oxide itself and present the insignificant role of diffused interstitial oxygen in the underlying Nb by regrowing a new oxide \textit{via} wet oxidation which reveals a mitigation of aggravated TLS losses. We hypothesize that such vacancies in the pentoxide serve as magnetic impurities and are a source of TLS-driven RF loss.

References in corpus (4)

• Investigation of microwave loss induced by oxide regrowth in high-Q Nb resonators
• Elucidating the local atomic and electronic structure of amorphous oxidized superconducting niobium films
• High-Field Q-slope Mitigation due to Impurity Profile in Superconducting Radio-Frequency Cavities
• RF surface resistance tuning of superconducting niobium via thermal diffusion of native oxide

Cited by in corpus (6)

• Correlating Superconducting Qubit Performance Losses to Sidewall Near-Field Scattering via Terahertz Nanophotonics
• Signatures of Enhanced Superconducting Properties in Niobium Cavities
• Fabrication effects on Niobium oxidation and surface contamination in Niobium-metal bilayers using X-ray photoelectron spectroscopy
• Quantifying Trapped Magnetic Vortex Losses in Niobium Resonators at mK Temperatures
• Surface Optimization of Superconducting Aluminum Resonators for Robust Quantum Device Fabrication
• Experimental Observation of Short-Range Magnetic Correlations in Amorphous Nb${}_2$O${}_5$ and Ta${}_2$O${}_5$ Thin Films