paper

Statistical Mechanics of Unconfined Systems: Challenges and Lessons

arXiv:2108.10895 · doi:10.3390/psf2021003008

Abstract

Motivated by applications of statistical mechanics in which the system of interest is spatially unconfined, we present an exact solution to the maximum entropy problem for assigning a stationary probability distribution on the phase space of an unconfined ideal gas in an anti-de Sitter background. Notwithstanding the gas's freedom to move in an infinite volume, we establish necessary conditions for the stationary probability distribution to be normalizable. As a part of our analysis, we develop a novel method for identifying dynamical constraints based on local measurements. With no appeal to \emph{a priori} information about globally-defined conserved quantities, it is thereby applicable to a much wider range of problems.

References in corpus (6)