Characterizing accelerated precipitation in proton irradiated steel

Abstract

Ion irradiation provides a promising substitute to neutron tests for investigating the effects of radiation on materials for fission and fusion reactor plants. Here we show proton irradiation can quantitatively reproduce precipitation that leads to embrittlement in reactor pressure vessel steels, at dose rates 10,000 times greater than experienced in fission reactor operation. Small-angle neutron scattering (SANS) is used to characterize precipitate size distributions in copper-containing steels irradiated to average doses of approx. 7 mdpa with 5 MeV protons. Comparing our results with the literature on reactor pressure vessel steels containing at least 1 at.% nickel, we find a power-law scaling of dose with exponent 0.25--0.30 accounts for the effects of dose rate on precipitate volume fraction over 6 orders of magnitude in dose rate. In conjunction with dose rate, carbon is identified as performing a leading role in determining precipitate sizes, adding to the known effects of nickel, manganese and irradiation temperature. We discuss the composition of precipitates inferred from SANS, taking previous atom probe tomography studies into consideration.

arXiv comment18 pages, 9 figures

References in corpus (6)

• Solute diffusion by self-interstitial defects and radiation-induced segregation in ferritic Fe-X (X=Cr, Cu, Mn, Ni, P, Si) dilute alloys
• Thermodynamics and kinetics of core-shell versus appendage co-precipitation morphologies: An example in the Fe-Cu-Mn-Ni-Si system
• The dominant mechanisms for the formation of solute-rich clusters in low-Cu steels under irradiation
• Effects of dilute substitutional solutes on carbon in $\alpha$-Fe: interactions and associated carbon diffusion from first-principles calculations
• First-principles investigation of magnetism and electronic structures of substitutional $3d$ transition-metal impurities in bcc Fe
• Magnetic and structural studies of G-phase compound Mn${}_6$Ni${}_{16}$Si${}_7$