Effect of Topology on the Conformations of Ring Polymers

Abstract

The bond fluctuation method is used to simulate both non-concatenated entangled and interpenetrating melts of ring polymers. We find that the swelling of interpenetrating rings upon dilution follows the same laws as for linear chains. Knotting and linking probabilities of ring polymers in semi-dilute solution are analyzed using the HOMFLY polynomial. We find an exponential decay of the knotting probability of rings. The correlation length of the semi-dilute solution can be used to superimpose knotting data at different concentrations. A power law dependence $f_n\sim \varphi R^2\sim {\varphi }^{0.77}N$ for the average number $f_n$ of linked rings per ring at concentrations larger than the overlap volume fraction of rings ${\varphi }^{\ast }$ is determined from the simulation data. The fraction of non-concatenated rings displays an exponential decay $P_{OO}\sim \exp (-f_n)$, which indicates $f_n$ to provide the entropic effort for not forming concatenated conformations. Based upon this results we find four different regimes for the conformations of rings in melts that are separated by a critical lengths $N_{OO}$, $N_C$ and $N^{\ast }$. $N_{OO}$ describes the onset of the effect of non-concatenation below which topological effects are not important, $N_C$ is the cross-over between weak and strong compression of rings, and $N^{\ast }$ is defined by the cross-over from a non-concatenation contribution $f_n\sim \varphi R^2$ to an overlap dominated concatenation contribution $f_n\sim \varphi N^{1/2}$ at $N>N^{\ast }$. For $N_{OO}<N<N_C$, the scaling of ring sizes $R\sim N^{2/5}$ results from balancing non-concatenation with weak compression of rings. For $N_C<N<N^{\ast }$, non-concatenation and strong compression imply $R\sim N^{3/8}$. Our simulation data for non-interpenetrating rings up to $N=1024$ are in good agreement with the prediction for weakly compressed rings.

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• Olympic Gels: Concatenation and Swelling
• Reversible stepwise condensation polymerization with cyclization: strictly alternating co-polymerization and homopolymerization based upon two orthogonal reactions