Time evolution of CO ro-vibrational excitation in a nanosecond discharge measured with quantum cascade laser absorption spectroscopy
arXiv:2102.09646 · doi:10.1088/1361-6463/ac03e7
Abstract
CO dissociation stimulated by vibrational excitation in non-equilibrium discharges has drawn lots of attention. Ns-discharges are known for their highly non-equilibrium conditions. It is therefore of interest to investigate the CO excitation in such discharges. In this paper, we demonstrate the ability for monitoring the time evolution of CO ro-vibrational excitation with a well-selected wavelength window around 2289.0 cm and a single CW quantum cascade laser (QCL) with both high accuracy and temporal resolution. The rotational and vibrational temperatures for both the symmetric and the asymmetric modes of CO in the afterglow of CO + He ns-discharge were measured with a temporal resolution of 1.5 s. The non-thermal feature and the preferential excitation of the asymmetric stretch mode of CO were experimentally observed, with a peak temperature of = 966 1.5 K, = 438.4 1.2 K and = 334.6 0.6 K reached at 3 s after the nanosecond pulse. In the following relaxation process, an exponential decay with a time constant of 69 s was observed for the asymmetric stretch (001) state, consistent with the dominant deexcitation mechanism due to VT transfer with He and deexcitation on the wall. Furthermore, a synchronous oscillation of the gas temperature and the total pressure was also observed and can be explained by a two-line thermometry and adiabatic process. The period of the oscillation and its dependence on the gas components is consistent with a standing acoustic wave excited by the ns-discharge.