Role of precursor composition in the polymorph transformations, morphology control and ferromagnetic properties of nanosized TiO${}_2$

Abstract

Pure phase and mixed phase TiO${}_2$ nanoparticles have been produced using a pyrolytic method from a non-aqueous carboxylate precursor. The precursor was prepared by a multiphase cation exchange using pentanoic acid (C${}_4$H${}_9$COOH). The thermal stability, polymorph content, morphology, size distribution and surface region of the produced nanoparticles were studied by TGA/DSC, XRD, FTIR and TEM. High quality monodisperse nanoparticles have been produced in the size range from 7 to 27 nm. The nanoparticles showed room temperature ferromagnetism revealed by VSM within bound polaron model. The carboxylate precursor is a good alternative to standard sol-gel to produce nanoparticles free from impurities.