Distinct magnetic ground states of $R_2$ZnIrO${}_6$ ($R$ = La and Nd) determined by neutron powder diffraction

Abstract

Double perovskite iridates $A_2$ZnIrO${}_6$ ($A$ = alkaline or lanthanide) show complex magnetic behaviors ranging from weak ferromagnetism to successive antiferromagnetic transitions. Here we report the static ($dc$) and dynamic ($ac$) magnetic susceptibility, and neutron powder diffraction measurements for $A$ = La and Nd compounds to elucidate the magnetic ground state. Below 10~K, the $A$ = La compound is best described as canted iridium moments in an antiferromagnet arrangement with a propagation vector \textbf{k} = 0 and a net ferromagnetic component along the $c$-axis. On the other hand, Nd${}_2$ZnIrO${}_6$ is described well as an antiferromagnet with a propagation vector \textbf{k} = (1/2~1/2~0) below $T_{\mathrm{N}}\sim$ 17 K. Scattering from both the Nd and Ir magnetic sublattices were required to describe the data and both were found to lie almost completely within the $ab$-plane. $Dc$ susceptibility revealed a bifurcation between the zero-field-cooled and field-cooled curves below $\sim$13 K in Nd${}_2$ZnIrO${}_6$. A glassy state was ruled out by $ac$ susceptibility but detailed magnetic isotherms revealed the opening of the loop below 13~K. These results suggest a delicate balance exists between the Dzyaloshinskii-Moriya, crystal field schemes, and $d$-$f$ interaction in this series of compounds.

6 pages, 5 figures. To be published in PRB