A Microscopic Theory of Softness in Supercooled Liquids

Abstract

We introduce a new measure of the structure of a liquid which is the softness of the mean-field potential developed by us earlier. We find that this softness is sensitive to small changes in the structure. We then study its correlation with the supercooled liquid dynamics. The study involves a wide range of liquids (fragile, strong, attractive, repulsive, and active) and predicts some universal behaviours like the softness is linearly proportional to the temperature and inversely proportional to the activation barrier of the dynamics with system dependent proportionality constants. We write down a master equation between the dynamics and the softness parameter and show that indeed the dynamics when scaled by the temperature and system dependent parameters show a data collapse when plotted against softness. The dynamics of fragile liquids show a strong softness dependence whereas that of strong liquids show a much weaker softness dependence. We also connect the present study with the earlier studies of softness involving machine learning (ML) thus providing a theoretical framework for understanding the ML results.

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• Identifying structural signature of dynamical heterogeneity via the local softness parameter
• Dynamic heterogeneity in polydisperse systems: A comparative study of the role of local structural order parameter and particle size
• The Influence of Particle Softness on Active Glassy Dynamics
• Effective structure of a system with continuous polydispersity
• Exploring the Relationship Between Softness and Excess Entropy in Glass-forming Systems
• Comparing zero-parameter theories for the WCA and harmonic-repulsive melting lines
• Theory of Generalized Hertzian Hyperspheres
• Replica Field Theory for a Generalized Franz--Parisi Potential of Inhomogeneous Glassy Systems: New Closure and the Associated Self-Consistent Equation
• Does mesoscopic elasticity control viscous slowing down in glassforming liquids?
• Structure-Dynamics Correlation and Its Link to Fragility and Dynamic Heterogeneity
• Density-Independent transient caging in the high-density phase of motility-induced phase separation