Methanimine as a key precursor of imines in the interstellar medium: the case of propargylimine

Abstract

A gas-phase formation route is proposed for the recently detected propargylimine molecule. In analogy to other imines, such as cyanomethanimine, the addition of a reactive radical (C${}_2$H in the present case) to methanimine (CH${}_2$NH}) leads to reaction channels open also in the harsh conditions of the interstellar medium. Three possible isomers can be formed in the C$H_2$NH + C${}_2$H reaction: Z- and E-propargylimine (Z-,E-PGIM) as well as N-ethynyl-methanimine (N-EMIM). For both PGIM species, the computed global rate coefficient is nearly constant in the 20-300 K temperature range, and of the order of 2-3 $\times$ 10${}^{-10}$ cm${}^3$ molecule${}^{-1}$ s${}^{-1}$, while that for N-EMIM is about two orders of magnitude smaller. Assuming equal destruction rates for the two isomers, these results imply an abundance ratio for PGIM of [Z]/[E] $\sim$ 1.5, which is only slightly underestimated with respect to the observational datum.

arXiv comment10 pages, 4 figures, 2 tables. Accepted in ApJL

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Cited by in corpus (4)

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• The origin of the E/Z isomer ratio of imines in the interstellar medium
• A sequential acid-base (SAB) mechanism in the interstellar medium: The emergence of cis formic acid in dark molecular clouds
• Formation of phosphorus monoxide (PO) in the interstellar medium: insights from quantum-chemical and kinetic calculations