Long-Term Stabilization of Two-Dimensional Perovskites by Encapsulation with Hexagonal Boron Nitride

Abstract

Metal halide perovskites are known to suffer from rapid degradation, limiting their direct applicability. Here, the degradation of phenethylammonium lead iodide (PEA2PbI4) two-dimensional perovskites under ambient conditions is studied using fluorescence, absorbance and fluorescence lifetime measurements. It is demonstrated that a long-term stability of two-dimensional perovskites can be achieved through the encapsulation with hexagonal boron nitride. While un-encapsulated perovskite flakes degrade within hours, the encapsulated perovskites are stable for at least three months. In addition, encapsulation considerably improves the stability under laser irradiation. The environmental stability, combined with the improved durability under illumination, is a critical ingredient for thorough spectroscopic studies of the intrinsic opto-electronic properties of this material platform.

arXiv comment10 pages, 4 figures, and supporting information

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• Revealing giant exciton fine-structure splitting in 2D perovskites using van der Waals passivation
• Temperature induced giant shift of phonon energy in epitaxial boron nitride layers
• Rapid spin depolarization in the layered 2D Ruddlesden Popper perovskite (BA)(MA)PbI
• Room-temperature polariton condensate in a two-dimensional hybrid perovskite