Theoretical investigation of a polarizable colloid in the salt medium
arXiv:2008.06751 · doi:10.1016/j.chemphys.2018.08.006
Abstract
In the present work, we have extended a weak coupling theory [A. Bakhshandeh, A. P. dos Santos and Y. Levin Phys. Rev. Lett 107, 107801 (2011)] for systems with added 1:1 electrolyte. To study the accuracy of the developed theory, we compare its numerical predictions with Monte Carlo simulation data and a recent theory which accounts for the surface polarization. A very good agreement is found for the case of monovalent electrolytes, up to very high salt concentrations and different colloidal charges
References in corpus (13)
- Electrostatic correlations: from Plasma to Biology
- Image charges in spherical geometry: Application to colloidal systems
- Liquid-state theory of charged colloids
- Simulation of Charged Systems in Heterogeneous Dielectric Media via a True Energy Functional
- Bjerrum Pairs in Ionic Solutions: a Poisson-Boltzmann Approach
- Weak and Strong Coupling Theories for Polarizable Colloids and Nano-Particles
- The electrical double layer for a fully asymmetric electrolyte around a spherical colloid: an integral equation study
- Asymmetric Coulomb fluids at randomly charged dielectric interfaces: Anti-fragility, overcharging and charge inversion
- Electrostatics of Patchy Surfaces
- Interaction between random heterogeneously charged surfaces in an electrolyte solution
- A simulational and theoretical study of the spherical electrical double layer for a size-asymmetric electrolyte: the case of big coions
- Ionic structure around polarizable metal nanoparticles in aqueous electrolytes
- Electrostatic Attraction between Overall Neutral Surfaces
Cited by in corpus (7)
- Interaction between charge-regulated metal nanoparticles in an electrolyte solution
- Reactive Monte Carlo Simulations for Charge Regulation of Colloidal Particles
- Equilibrium conformations and surface charge regulation of spherical polymer brushes in stretched regimes
- Adsorption of polyelectrolytes on charged microscopically patterned surfaces
- Interaction between two overall neutral charged microscopically patterned surfaces
- Electrolytes in regimes of strong confinements: surface charge modulations, osmotic equilibrium and electroneutrality
- Charge fluctuations in charge regulated systems: dependence on statistical ensemble