Shear-induced polydomain structures of nematic lyotropic chromonic liquid crystal disodium cromoglycate

Abstract

Lyotropic chromonic liquid crystals (LCLCs) represent aqueous dispersions of organic disk-like molecules that form cylindrical aggregates. Despite the growing interest in these materials, their flow behavior is poorly understood. Here, we explore the effect of shear on dynamic structures of the nematic LCLC, formed by 14wt $\%$ water dispersion of disodium cromoglycate (DSCG). We employ in-situ polarizing optical microscopy (POM) and small-angle and wide-angle X-ray scattering (SAXS/WAXS) to obtain independent and complementary information on the director structures over a wide range of shear rates. The DSCG nematic shows a shear-thinning behavior with two shear-thinning regions (Region I at $\dot{\gamma }<1s^{-1}$ and Region III at $\dot{\gamma }>10s^{-1}$) separated by a pseudo-Newtonian Region II ($1s^{-1}<\dot{\gamma }<10s^{-1}$). The material is of a tumbling type. In Region I, $\dot{\gamma }<1s^{-1}$, the director realigns along the vorticity axis. An increase of $\dot{\gamma }$ above $1s^{-1}$ triggers nucleation of disclination loops. The disclinations introduce patches of the director that deviates from the vorticity direction and form a polydomain texture. Extension of the domains along the flow and along the vorticity direction decreases with the increase of the shear rate to $10s^{-1}$. Above $10s^{-1}$, the domains begin to elongate along the flow. At $\dot{\gamma }>100s^{-1}$, the texture evolves into periodic stripes in which the director is predominantly along the flow with left and right tilts. The period of stripes decreases with an increase of $\dot{\gamma }$. The shear-induced transformations are explained by the balance of the elastic and viscous energies. In particular, nucleation of disclinations is associated with an increase of the elastic energy at the walls separating nonsingular domains with different director tilts.

References in corpus (6)

• Living Liquid Crystals
• Command of active matter by topological defects and patterns
• Topological structure and dynamics of three dimensional active nematics
• Effect of collective molecular reorientations on Brownian motion of colloids in nematic liquid crystal
• Lyotropic chromonic liquid crystal semiconductors for water-solution processable organic electronics
• Ionic content dependence of viscoelasticity of lyotropic chromonic liquid crystal sunset yellow

Cited by in corpus (6)

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