Symmetry breaking in single crystal SrTiO${}_3$ plates: EPR manifestations

Abstract

Electron paramagnetic resonance studies of the impurity Fe${}^{3+}$ and Mn${}^{4+}$ centers indicate that the symmetry of the crystal structure of millimeter-scale strontium titanate plates above 105 K lowers in the bulk from cubic to tetragonal, different from that of the conventional low-temperature antiferrodistortive phase. It is shown that the effect does not originate from the residual stress; its magnitude (observed tetragonal distortion) and particular manifestations depend on plate orientation, surface quality and the geometry of a sample. Peculiarities of the observed phenomenon are presented and possible scenario of its realization is discussed.

14 pages, 4 figures