Steering alkyne homocoupling with on-surface synthesized catalysts
arXiv:2006.12818 · doi:10.1039/D0CC03779F
Abstract
We report a multi-step on-surface synthesis strategy. The first step consists in the surface-supported synthesis of metal-organic complexes, which are subsequently used as catalysts to steer on-surface alkyne coupling reactions. In addition, we analyze and compare the electronic properties of the different coupling motifs obtained.
References in corpus (6)
- The mechanism of high-resolution STM/AFM imaging with functionalized tips
- Long-range repulsive interaction between TTF molecules on a metal surface induced by charge transfer
- Tailoring topological order and π-conjugation to engineer quasi-metallic polymers
- Electronic structure tunability by periodic meta-ligand spacing in one-dimensional organic semiconductors
- Non-Covalent Dimerization after Enediyne Cyclization on Au(111)
- Controlling the stereospecific bonding motif of Au-thiolate links