Cold collisions of C${}_2^{-}$ anions with Li and Rb atoms in hybrid traps

Abstract

We present a theoretical investigation of reactive and non-reactive collisions of Li and Rb atoms with C${}_2^{-}$ molecular anions at low temperatures in the context of sympathetic cooling in hybrid trap experiments. Based on recently reported accurate potential energy surfaces for the singlet and triplet states of the Li-C${}_2^{-}$ and Rb-C${}_2^{-}$ systems, we show that the associative electronic detachment reaction is slow if the colliding partners are in their ground state, but fast if they are excited. The results are expected to be representative of the alkali-metal series. We also investigate rotationally inelastic collisions in order to explore the cooling of the translational and rotational degrees of freedom of C${}_2^{-}$ in hybrid ion-atom traps. The effect of micromotion is taken into account by considering Tsallis distributions of collision energies. We show that the translational cooling occurs much more rapidly than rotational cooling and that the presence of excited atoms leads to losses of anions on a timescale comparable to that of rotational cooling.

arXiv commentICPEAC 2019 conference

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Cited by in corpus (1)

• Generation of rotational ground state HD${}^{+}$ ions in an ion trap using a resonance-enhanced threshold photoionization process