Topological Nodal Line Electrides: Realization of Ideal Nodal Line State Nearly Immune from Spin-Orbit Coupling

Abstract

Nodal line semimetals (NLSs) have attracted broad interest in current research. In most of existing NLSs, the intrinsic properties of nodal lines are greatly destroyed because nodal lines usually suffer sizable gaps induced by non-negligible spin-orbit coupling (SOC). In this work,we propose the topological nodal line electrides (TNLEs), which achieve electronic structures of nodal lines and electrides simultaneously, provide new insight on designing excellent NLSs nearly immune from SOC. Since the states near the Fermi level are most contributed by nonnucleus-bounded interstitial electrons, nodal lines in TNLEs manifest extremely small SOCinduced gap even possessing heavy elements. Especially, we propose the family of A2B (A = Ca, Sr, Ba; B= As, Sb, Bi) materials are realistic TNLEs with negligible SOC-induced gaps, which can play as excellent platforms to study the intrinsic properties of TNLEs

References in corpus (10)

• Weyl semimetal phase in non-centrosymmetric transition metal monophosphides
• Phase transition between the quantum spin Hall and insulator phases in 3D: emergence of a topological gapless phase
• Classification of stable three-dimensional Dirac semimetals with nontrivial topology
• Topological Node-Line Semimetal in Three Dimensional Graphene Networks
• Topological nodal line semimetals
• Topological Nodal Line Semimetals in CaP3 family of materials
• Topological surface electronic states in candidate nodal-line semimetal CaAgAs
• From Type-II Triply Degenerate Nodal Points and Three-Band Nodal Rings to Type-II Dirac Points in Centrosymmetric Zirconium Oxide
• Topological Phase with Critical-Type Nodal Line State in Intermetallic CaPd
• Transverse Shift in Andreev Reflection