Charge transfer energy in iridates: a hard x-ray photoelectron spectroscopy study

Abstract

We have investigated the electronic structure of iridates in the double perovskite crystal structure containing either Ir${}^{4+}$ or Ir${}^{5+}$ using hard x-ray photoelectron spectroscopy. The experimental valence band spectra can be well reproduced using tight binding calculations including only the Ir $5d$, O $2p$ and O $2s$ orbitals with parameters based on the downfolding of the density-functional band structure results. We found that regardless of the A and B cations, the A${}_2$BIrO${}_6$ iridates have essentially zero O $2p$ to Ir $5d$ charge transfer energies. Hence, double perovskite iridates turn out to be extremely covalent systems with the consequence being that the magnetic exchange interactions become very long-ranged, thereby hampering the materialization of the long-sought Kitaev physics. Nevertheless, it still would be possible to realize a spin-liquid system using the iridates with a proper tuning of the various competing exchange interactions.

9 pages, 7 figures, submitted to Physical Review B