On the Hellmann-Feynman theorem in statistical mechanics
arXiv:2004.04018 · doi:10.1016/j.physleta.2020.126531
Abstract
In this paper we develop the Hellmann-Feynman theorem in statistical mechanics without resorting to the eigenvalues and eigenvectors of the Hamiltonian operator. Present approach does not require the quantum-mechanical version of the theorem at and bypasses any discussion about degenerate states.