Importance of site occupancy and absence of strain glassy phase in NiFeMnIn
arXiv:2004.00256 · doi:10.1016/j.jallcom.2019.05.172
Abstract
Martensitic transition temperature steadily decreases in NiFeMnIn and is completely suppressed at = 0.2. Despite suppression of martensitic transition, NiFeMnIn does not display the expected strain glassy phase. Instead, a ground state with dominant ferromagnetic interactions is observed. A study of structural and magnetic properties of = 0.2 reveal that the alloy consists of a major Fe rich cubic phase and a minor Fe deficient monoclinic phase favoring a ferromagnetic ground state. This is exactly opposite of that observed in NiMnFeIn wherein a strain glassy phase is observed for = 0.1. The change in site symmetry of Fe when doped for Ni in contrast to Mn in the Heusler composition seems to support the growth of the ferromagnetic phase.
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