Unified analytic expressions for the entanglement length, tube diameter, and plateau modulus of polymer melts

Abstract

By combining molecular dynamics simulations and topological analyses with scaling arguments, we obtain analytic expressions that quantitatively predict the entanglement length $N_e$, the plateau modulus $G$, and the tube diameter $a$ in melts that span the entire range of chain stiffnesses for which systems remain isotropic. Our expressions resolve conflicts between previous scaling predictions for the loosely entangled [Lin-Noolandi: $G{\ell }_K^3/k_{\text{B}}T\sim ({\ell }_K/p{)}^3$], semiflexible [Edwards/de Gennes: $G{\ell }_K^3/k_{\text{B}}T\sim ({\ell }_K/p{)}^2$], and tightly-entangled [Morse: $G{\ell }_K^3/k_{\text{B}}T\sim ({\ell }_K/p{)}^{1+\epsilon }$] regimes, where ${\ell }_K$ and $p$ are respectively the Kuhn and packing lengths. We also find that maximal entanglement (minimal $N_e$) coincides with the onset of local nematic order.

Accepted for publication in Physical Review Letters

References in corpus (1)

• Viscoelasticity and primitive path analysis of entangled polymer liquids: From f-actin to polyethylene

Cited by in corpus (3)

• Facile equilibration of well-entangled semiflexible bead-spring polymer melts
• Entanglement kinetics in polymer melts are chemically specific
• Activity-Induced Stiffness, Entanglement Network and Dynamic Slowdown in Unentangled Semidilute Polymer Solutions