Microscopic Origins of the Swim Pressure and the Anomalous Surface Tension of Active Matter
arXiv:1912.11727 · doi:10.1103/PhysRevE.101.012604
Abstract
The unique pressure exerted by active particles -- the "swim" pressure -- has proven to be a useful quantity in explaining many of the seemingly confounding behaviors of active particles. However, its use has also resulted in some puzzling findings including an \textit{extremely negative} surface tension between phase separated active particles. Here, we demonstrate that this contradiction stems from the fact that the swim pressure \textit{is not a true pressure}. At a boundary or interface, the reduction in particle swimming generates a net active force density -- an entirely \textit{self-generated body force}. The pressure at the boundary, which was previously identified as the swim pressure, is in fact an elevated (relative to the bulk) value of the \textit{traditional particle pressure} that is generated by this interfacial force density. Recognizing this unique mechanism for stress generation allows us to define a much more physically plausible surface tension. We clarify the utility of the swim pressure as an "equivalent pressure" (analogous to those defined from electrostatic and gravitational body forces) and the conditions in which this concept can be appropriately applied.
Submitted June 6, 2019; to appear in Physical Review E. Main text with appendices (8 pages, 6 figures) and Supplemental Material (2 pages, 1 figure). Supplemental videos available upon request or at https://drive.google.com/drive/folders/14Isyut7SRvyrb8PfTwucVcZIPhonh8Ax?usp=sharing
References in corpus (8)
- Motility-Induced Phase Separation
- Strong scaling of general-purpose molecular dynamics simulations on GPUs
- Pressure and Phase Equilibria in Interacting Active Brownian Spheres
- Towards a 'Thermodynamics' of Active Matter
- Clausius relation for active particles: what can we learn from fluctuations?
- Non-Equilibrium Surface Tension of the Vapour-Liquid Interface of Active Lennard-Jones Particles
- The curved kinetic boundary layer of active matter
- Swimming to Stability: Structural and Dynamical Control via Active Doping