Transverse viscous transport in classical solids

Abstract

The transverse velocity time correlation function ${\tilde{C}}_{\mathrm{T}}(k,\omega )$ with $k$ and $\omega$ being the wavenumber and the frequency, respectively, is a fundamental quantity in determining the transverse mechanical and transport properties of materials. In ordinary liquids, a nonzero value of ${\tilde{C}}_{\mathrm{T}}(k,0)$ is inevitably associated with viscous material flows. Curiously, even in solids where significant material flows are precluded due to frozen positional degrees of freedom, molecular dynamics simulations reveal that ${\tilde{C}}_{\mathrm{T}}(k,0)$ certainly takes a nonzero value, and in consequence, the time integration of the velocity field shows definite diffusive behavior with diffusivity ${\tilde{C}}_{\mathrm{T}}(k,0)/3$. We demonstrate that this diffusive behavior can be attributed to a solid-specific viscous transport. The resultant viscosity is interpreted as the renormalized viscosity accounting for the nonlinear inertia effect.

8pages, 5figures