Liquid Crystal Distortions Revealed by an Octupolar Tensor

Abstract

The classical theory of liquid crystal elasticity as formulated by Oseen and Frank describes the (orientable) optic axis of these soft materials by a director $\mathbf{n}$. The ground state is attained when $\mathbf{n}$ is uniform in space; all other states, which have a non-vanishing gradient $\nabla \mathbf{n}$, are distorted. This paper proposes an algebraic (and geometric) way to describe the local distortion of a liquid crystal by constructing from $\mathbf{n}$ and $\nabla \mathbf{n}$ a third-rank, symmetric and traceless tensor $\mathbf{A}$ (the octupolar tensor). The (nonlinear) eigenvectors of $\mathbf{A}$ associated with the local maxima of its cubic form $\Phi$ on the unit sphere (its octupolar potential) designate the directions of distortion concentration. The octupolar potential is illustrated geometrically and its symmetries are charted in the space of distortion characteristics, so as to educate the eye to capture the dominating elastic modes. Special distortions are studied, which have everywhere either the same octupolar potential or one with the same shape, but differently inflated.

References in corpus (5)

• Interpretation of saddle-splay and the Oseen-Frank free energy in liquid crystals
• Landau theory for helical nematic phases
• Octupolar order in two dimensions
• Classification of nematic order in 2+1D: Dislocation melting and $O(2)/Z_N$ lattice gauge theory
• Generic first-order phase transitions between isotropic and orientational phases with polyhedral symmetries