Contributions of magnetic structure and nitrogen to perpendicular magnetocrystalline anisotropy in antiperovskite $\epsilon$-Mn${}_4$N

Abstract

To study how nitrogen contributes to perpendicular magnetocrystalline anisotropy (PMA) in the ferrimagnetic antiperovskite Mn${}_4$N, we examined both the fabrication of epitaxial Mn${}_4$N films with various nitrogen contents and first-principles density-functional calculations. Saturation magnetization ($M_{\mathrm{s}}$) peaks of 110 mT and uniaxial PMA energy densities ($K_{\mathrm{u}}$) of 0.1 MJ/m${}^3$ were obtained for a N${}_2$ gas flow ratio ($Q$) of $\sim 10\%$ during sputtering deposition, suggesting nearly single-phase crystalline $\epsilon$-Mn${}_4$N. Segregation of $\alpha$-Mn and nitrogen-deficient Mn${}_4$N grains was observed for $Q\approx 6\%$, which was responsible for a decrease in the $M_{\mathrm{s}}$ and $K_{\mathrm{u}}$. The first-principles calculations revealed that the magnetic structure of Mn${}_4$N showing PMA was "type-B" having a collinear structure, whose magnetic moments couple parallel within the c-plane and alternating along the c-direction. In addition, the $K_{\mathrm{u}}$ calculated using Mn${}_{32}$N${}_x$ supercells showed a strong dependence on nitrogen deficiency, in qualitative agreement with the experimental results. The second-order perturbation analysis of $K_{\mathrm{u}}$ with respect to the spin-orbit interaction revealed that not only spin-conserving but also spin-flip processes contribute significantly to the PMA in Mn${}_4$N. We also found that both contributions decreased with increasing nitrogen deficiency, resulting in the reduction of $K_{\mathrm{u}}$. It was noted that the decrease in the spin-flip contribution occurred at the Mn atoms in face-centered sites. This is one of the specific PMA characteristics we found for antiperovskite-type Mn${}_4$N.

arXiv comment38 pages, 9 figures, 1 table

References in corpus (5)

• High spin polarization in epitaxial films of ferrimagnetic Mn3Ga
• Magnetic stress as a driving force of structural distortions: the case of CrN
• Origin of perpendicular magneto-crystalline anisotropy in L10-FeNi under tetragonal distortion
• Magnetism of iron: from the bulk to the monoatomic wire
• Perpendicular magnetic anisotropy at the Fe/MgAl${}_2$O${}_4$ interface: Comparative first-principles study with Fe/MgO

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