Probing weakly hybridized magnetic molecules by spin-polarized tunneling

Abstract

Advances in molecular spintronics rely on the in-depth characterization of the molecular building blocks in terms of their electronic and, more importantly, magnetic properties. For this purpose, inert substrates that interact only weakly with adsorbed molecules are required in order to preserve their electronic states. Here, we investigate the magnetic-field response of a single paramagnetic 5,5-dibromosalophenatocobalt(II) (CoSal) molecule adsorbed on a weakly interacting magnetic substrate, namely Fe-intercalated graphene (GR/Fe) grown on Ir(111), by using spin-polarized scanning tunneling microscopy and spectroscopy (SP-STM/STS). We have obtained local magnetization curves, spin-dependent tunneling spectra, and spatial maps of magnetic asymmetry for a single CoSal molecule, revealing its magnetic properties and coupling to the local environment. The distinct magnetic behavior of the Co-metal center is found to rely strictly on its position relative to the GR/Fe moire structure, which determines the level of hybridization between the GR/Fe surface pi-system, the molecular ligand pi-orbitals and the molecular Co-ion d-orbital.

arXiv comment15 pages, 3 figures

References in corpus (4)

• Controlling the Local Spin-Polarization at the Organic-Ferromagnetic Interface
• Spin- and energy-dependent tunneling through a single molecule with intramolecular spatial resolution
• Visualizing the spin of individual molecules
• Ferromagnetic and Antiferromagnetic Coupling of Spin Molecular Interfaces with High Thermal Stability

Cited by in corpus (4)

• Independent and coherent transitions between antiferromagnetic states of few-molecule systems
• Time-dependent spintronic anisotropy in magnetic molecules
• Graphene decoupling through oxygen intercalation on Gr/Co and Gr/Co/Ir interfaces
• Image-potential states on a 2D Gr-ferromagnet hybrid: enhancing spin and stacking sensing